[1]李广学,李广田,马建华,等.大豆油的环氧化反应宏观动力学研究[J].东南大学学报(自然科学版),2001,31(1):107-108.[doi:10.3969/j.issn.1001-0505.2001.01.024]
 Li Guangxue,Li Guangtian,Ma Jianhua,et al.Research of the Epoxidation Kinetics of the Soy Bean Oil[J].Journal of Southeast University (Natural Science Edition),2001,31(1):107-108.[doi:10.3969/j.issn.1001-0505.2001.01.024]
点击复制

大豆油的环氧化反应宏观动力学研究()
分享到:

《东南大学学报(自然科学版)》[ISSN:1001-0505/CN:32-1178/N]

卷:
31
期数:
2001年第1期
页码:
107-108
栏目:
化学化工
出版日期:
2001-01-20

文章信息/Info

Title:
Research of the Epoxidation Kinetics of the Soy Bean Oil
作者:
李广学 李广田 马建华 宋晓敏
淮南工业学院化工系,淮南 232001
Author(s):
Li Guangxue Li Guangtian Ma Jianhua Song Xianmin
Department of Chemistry and Chemical Engineering, Huainan Institute of Technology, Huainan 232001)
关键词:
大豆油 环氧化 宏观动力学
Keywords:
soy bean oil epoxidation macro-kinetics
分类号:
TQ410.2
DOI:
10.3969/j.issn.1001-0505.2001.01.024
摘要:
通过对环氧大豆油制备的小试和中试实验,给出了大豆油环氧化反应的最佳工艺条件,宏观动力学关系公式:rEO=d(EO)/dt=0.075 2.得出大豆油环氧化反应在该条件下为传质控制的结论.
Abstract:
By the lab and pilot experiments of the epoxidised soy bean oil preparation, the paper gives the optimal condition of the epoxidised soy bean oil preparation and the epoxidation macro-kinetics formula: rEO=d(EO)/dt=0.075 2. The conclusion is that the epoxidation of soy bean oil is mass-transfer-determined.

参考文献/References:

[1] FMC Corp.Epoxidation of soy bean oil.US patent,3655698.1974-03-16
[2] Asahi Chemical Ind KK.Epoxidised soy bean oil production — using peractic acid,and separation with hexane.Japan patent,J76006685.1976-10-12
[3] Henkel Kgaa.Contious epoxidation especially of soya oil with per-formic acid — production in situ,using cascade of reactors operated with cross countercurrent flow.世界产权组织专利,WO8404920,1984-07-05
[4] 袁云程,陈宏博,高大彬.环氧化大豆油及棉子油的制备.精细化工,1991,8(1):31~33
[5] 郭学阳.环氧大豆油生产中一些技术问题的探讨.江苏化工,1989 (3):16~17
[6] 金素文.棉子油的环氧化工艺研究.华东化工学院学报,1984,10(4):531~536
[7] 广州永革化工厂.GB1677—81增塑剂环氧值的测定(盐酸-丙酮法).见:中国国家标准汇编,10分册.北京:中国标准出版社,1982.270~273

备注/Memo

备注/Memo:
作者简介:李广学,男,1966年生,在职硕士,讲师.
更新日期/Last Update: 2001-01-20