[1]邹志红,樊健.含4’-(1-咪唑基-亚甲基)苯甲酸盐配位聚合物的合成与表征[J].东南大学学报(自然科学版),2001,31(6):117-119.[doi:10.3969/j.issn.1001-0505.2001.06.028]
 Zou Zhihong,Fan Jian.Syntheses and Characterization of Coordination Polymers with 4’-(Imidazol-1-Ylmethyl)Benzoate[J].Journal of Southeast University (Natural Science Edition),2001,31(6):117-119.[doi:10.3969/j.issn.1001-0505.2001.06.028]
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含4’-(1-咪唑基-亚甲基)苯甲酸盐配位聚合物的合成与表征()
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《东南大学学报(自然科学版)》[ISSN:1001-0505/CN:32-1178/N]

卷:
31
期数:
2001年第6期
页码:
117-119
栏目:
化学化工
出版日期:
2001-11-20

文章信息/Info

Title:
Syntheses and Characterization of Coordination Polymers with 4’-(Imidazol-1-Ylmethyl)Benzoate
作者:
邹志红1 樊健2
1 东南大学化学化工系,南京 210096; 2 南京大学配位化学研究所,配位化学国家重点实验室,南京 210093
Author(s):
Zou Zhihong1 Fan Jian2
1 Department of Chemistry and Chemical Engineering, Southeast University,Nanjing 210096, China; 2 Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry,Nanjing University, Nanjing 210093, China)
关键词:
4’-(1-咪唑基-亚甲基)苯甲酸盐 配位聚合物 差热-热重分析 红外光谱 磁化率
Keywords:
4’-(Imidazol-1-ylmethyl)benzoate coordination polymer thermogravimetric and differential analyses infrared spectrum magnetic susceptibility
分类号:
O614
DOI:
10.3969/j.issn.1001-0505.2001.06.028
摘要:
合成了3个新的含4’-(1-咪唑基-亚甲基)苯甲酸盐的金属配合物,[M(imbz)2]·nH2O[M=Cu(II)、Ni(II)、Cd(II),imbz-=4’-(1-咪唑基-亚甲基)苯甲酸根,n=1或2],用元素分析、热分析、红外光谱、X射线粉末衍射分析及磁化率测定等方法对配合物结构的进行了表征.结果表明配体imbz-通过咪唑氮原子和羧基氧原子与金属离子配位形成了配位聚合物.
Abstract:
Three new metal complexes containing 4’-(Imidazol-1-ylmethyl)benzoate (imbz-), [M(imbz)2]·nH2O[M=Cu(II), Ni(II), Cd(II), n=1or 2] are synthesized and characterized by elemental analyses, thermogravimetric and differential analyses, infrared, X-ray powder diffraction and magnetic measurements. The results indicate that coordination polymers are formed by coordination of benzoate and imidazole groups to the metal ions.

参考文献/References:

[1] Kitagawa S,Kondo M.Functional micropore chemistry of crystalline metal complex-assembled compounds.Bull Chem Soc Jpn,1998,71(8):1739~1753
[2] Munakata M,Wu L P,Kuroda-Sowa T.Crystal engineering of multidimensional Copper(I) and Silver(I) coordination supermolecules and polymers with functions.Bull,Chem Soc Jpn,1997,70(8):1727~1743
[3] Liu H K,Sun W Y,Tang W X.Self-assembly of the first Copper(II) infinite 2D network with large cavities formed between the adjacent layers.Inorg Chem,1999,38(26):6313~6316
[4] Dong Y B,Layland R C,Smith M D.Syntheses and characterization of one-dimensional coordination polymers generated from Cadmium nitrate and bipyridine ligands.Inorg Chem,1999,38(13):3056~3060
[5] 曾锡瑞,熊仁根,游效曾.一种新型的T形一维镉配位化合物[Cd(C5H4NCOO)·(C5H5NCOO)·NO3·H2O]n.无机化学学报,2000,16(4),641~645
[6] Sun W Y,Zhang Y A,Okamura T.Synthesis and crystal structure of a new two-dimensional coordination polymer,{[CoII(imbz)2]·H2O}n [imbz-=4’-(Imidazol-1-ylmethyl)benzoate Anion].Chem Lett,2000,346(10):1222~1223
[7] Nakamoto K.Infrared and raman spectra of inorganic and coordination compounds.4th ed.New York:Wiley & Sons.1986,231~232

备注/Memo

备注/Memo:
作者简介:邹志红,女,1963生,硕士.
更新日期/Last Update: 2001-11-20