[1]孙越,王世和,傅大放,等.树脂吸附法处理TDI加氢还原生产废水[J].东南大学学报(自然科学版),2007,37(3):491-494.[doi:10.3969/j.issn.1001-0505.2007.03.027]
　Sun Yue,Wang Shihe,Fu Dafang,et al.Adsorption treatment of wastewater arising from hydrogenated deoxidization process in TDI production with polymeric resin[J].Journal of Southeast University (Natural Science Edition),2007,37(3):491-494.[doi:10.3969/j.issn.1001-0505.2007.03.027]
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树脂吸附法处理TDI加氢还原生产废水()
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《东南大学学报(自然科学版)》[ISSN:1001-0505/CN:32-1178/N]

卷:
37
期数:
2007年第3期
页码:
491-494
栏目:
环境科学与工程
出版日期:
2007-05-20

文章信息/Info

Title:
Adsorption treatment of wastewater arising from hydrogenated deoxidization process in TDI production with polymeric resin
作者:
孙越1;  王世和1;  傅大放1;  李爱民2;  张全兴2
1 东南大学土木工程学院, 南京 210096; 2 南京大学环境工程系, 南京 210093
Author(s):
Sun Yue1;  Wang Shihe1;  Fu Dafang1;  Li Aimin2;  Zhang Quanxing2
1 School of Civil Engineering, Southeast University, Nanjing 210096, China
2 Department of Environmental Engineering, Nanjing University, Nanjing 210093, China
关键词:
甲苯二异氰酸酯;  吸附树脂;  废水处理
Keywords:
tolylene diisocyanate;  polymeric adsorbent;  wastewater treatment
分类号:
X703.1
DOI:
10.3969/j.issn.1001-0505.2007.03.027
摘要:
研究了树脂吸附法处理甲苯二异氰酸酯(TDI)加氢还原生产废水的工艺过程.结果表明,NDA-8吸附树脂对该废水具有良好的吸附-脱附效果.经树脂吸附处理,废水中主要污染物2,4-二氨基甲苯和2,6-二氨基甲苯均得到完全去除,COD由6 300 mg/L降为150 mg/L以下,达到国家二级排放标准,采用稀盐酸可实现树脂的完全再生,高浓度脱附液经调碱和结晶,可回收2,4-二氨基甲苯和2,6-二氨基甲苯.
Abstract:
The polymeric resin NDA-8 was employed to treat the industrial wastewater from hydrogenated deoxidization process in tolylene diisocyanate(TDI)production and good performance of adsorption and desorption was shown. After adsorption process the two main pollutants in the wastewater, 2,4-diaminomethylbenzene and 2,6-diaminomethylbenzene, can be removed completely. The concentration of COD in the wastewater and the treated effluent are about 6 000 mg/L and less than 150 mg/L, respectively, which meets the national second standard. Meanwhile, dilute hydrochloric acid can be used as a solvent for complete regeneration of the spent adsorbent, and 2,4-diaminomethylbenzene and 2,6-diaminomethylbenzene can be recovered by the basification, crystallization and separation of the desorption solution.

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备注/Memo

备注/Memo:
作者简介: 孙越(1973—),男,博士,讲师,sycyseu@163.com.
更新日期/Last Update: 2007-05-20