[1]刘福生,王晟,吴敏,等.染料的合成、表征及其光热性能[J].东南大学学报(自然科学版),2008,38(6):1049-1053.[doi:10.3969/j.issn.1001-0505.2008.06.022]
 Liu Fusheng,Wang Sheng,Wu Min,et al.Synthesis and characterization of perylene dye and its optical and thermal properties[J].Journal of Southeast University (Natural Science Edition),2008,38(6):1049-1053.[doi:10.3969/j.issn.1001-0505.2008.06.022]
点击复制

染料的合成、表征及其光热性能()
分享到:

《东南大学学报(自然科学版)》[ISSN:1001-0505/CN:32-1178/N]

卷:
38
期数:
2008年第6期
页码:
1049-1053
栏目:
化学化工
出版日期:
2008-11-20

文章信息/Info

Title:
Synthesis and characterization of perylene dye and its optical and thermal properties
作者:
刘福生12 王晟3 吴敏1 孙岳明1
1 东南大学化学化工学院, 南京 210096; 2 南京林业大学化学与材料科学系, 南京 210037; 3 南京工业大学化学化工学院, 南京 210009
Author(s):
Liu Fusheng12 Wang Sheng3 Wu Min1 Sun Yueming1
1 School of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, China
2 Department of Chemistry and Materials Science, Nanjing Forestry University, Nanjing 210037, China
3 Institute of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
关键词:
染料 合成 表征 热重分析 荧光光谱
Keywords:
perylene dye synthesis characterization thermal gravimetric analysis fluorescence spectrum
分类号:
O62
DOI:
10.3969/j.issn.1001-0505.2008.06.022
摘要:
用3,4,9,10- 苝四羧酸二酐(PTCDA)、喹啉、无水醋酸锌和4-氨基吡啶(AP)合成了N,N’-二(4-吡啶基)-3,4,9,10-苝四羧酸二酰亚胺(DPPBI), 用元素分析、核磁共振(1H NMR和13C NMR)、红外光谱(FT-IR)、紫外可见光谱(UV-Vis)进行了结构表征. 用热重分析仪对产物进行了热重分析, 结果表明:该化合物5%的热失重温度为480 ℃左右, 具有优异的热稳定性能. 用分子荧光光度计对产物进行了荧光光谱分析, 在丙酮中的最大荧光发射强度位于524.5 nm. 以产物(DPPBI)为敏化剂敏化TiO2制备了DPPBI/TiO2粉末, 用紫外可见漫反射光谱(UV-Vis DRS)对DPPBI/TiO2进行了光吸收性能研究, 结果表明,DPPBI/TiO2在400~640 nm范围内有一较强吸收带, 光谱响应范围拓宽到了可见光区.
Abstract:
The N,N’-di(4-pyridyl)-3,4,9,10-perylene tetracarboxylic acid bisimide(DPPBI)was synthesized by 4-aminopyridine(AP), 3,4,9,10-perylenetetracarboxylic dianhydride(PTCDA), quinoline and anhydrous zinc acetate. The chemical structure of this compound was characterized by elemental analysis, 13C NMR, 1H NMR, FT-IR and UV-Vis. The thermal gravimetric analysis of DPPBI was studied. The results show that the temperature of 5% weight loss is about 480 ℃ and the DPPBI is a thermostable compound. The fluorescence spectrum of DPPBI were studied, the results show that the fluorescence intensity is strongest at 524.5 nm in acetone. The DPPBI/TiO2 powders were prepared using DPPBI sensitizing TiO2. The light absorption properties of DPPBI/TiO2 powders were studied by UV-Vis diffuse reflectance spectroscopy(UV-Vis DRS). The results show that DPPBI/TiO2 extends the optical absorption spectra from UV to visible light region(400 to 640 nm).

参考文献/References:

[1] Fujishima A,Honda K.Electrochemical photolysis of water at a semiconductor electron [J]. Nature,1972,238:37.
[2] Ni M,Leung M K H,Leung D Y C,et al.A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production [J].Ren Sust Energy Rev,2007,11(3):401-425.
[3] Fan L Q,Xu Y P,Tian H.1,6-Disubstituted perylene bisimides:concise synthesis and characterization as near-infrared fluorescent dyes [J]. Tetrahedron Lett,2005, 46(26):4443-4447.
[4] Kim J Y,Chung I J,Kim Y C,et al.Mobility of electrons and holes in a liquid crystalline perylene diimide thin film with time of flight technique [J]. Chem Phys Lett,2004, 398(4/5/6):367-371.
[5] Takahashia K,Nakajima I,Imoto K,et al.Sensitization effect by porphyrin in polythiophene/perylene dye two-layer solar cells [J].Sol Energy Mater Sol Cells,2003,76(1):115-124.
[6] Wang S,Li Y L,Du C M,et al.Dye sensitization of nanocrystalline TiO2 by perylene derivatives [J].Synth Met,2002, 128(3):299-304.
[7] Jung J,Rybak A,Slazak A,et al.Photogeneration and photovoltaic effect in blends of derivatives of hexabenzocoronene and perylene [J].Synth Met,2005, 155(1):150-156.
[8] Matsui M,Wang M X,Funabiki K,et al.Properties of novel perylene-3,4:9,10-tetracarboxidiimide-centred dendrimers and their application as emitters in organic electroluminescence devices [J]. Dyes and Pigments,2007,74(1):169-175.
[9] Fukuda M,Kodama K,Mito K.Perylene orange doped acrylic polymer for solid-state dye laser [J].Jpn J Appl Phys,Part 2:Lett,2001,40(5):440-442.
[10] Abe R,Sayama K,Arakawa H.Dye-sensitized photocatalysts for efficient hydrogen production from aqueous I-solution under visible light irradiation [J]. J Photochem Photobiol,A:Chem,2004,166(1/2/3):115-122.
[11] Dhanalakshmi K B,Latha S,Anandan S,et al.Dye sensitized hydrogen evolution from water [J].Int J Hydrogen Energy,2001, 26(7):669-674.
[12] Patsoura A,Kondarides D I,Verykios X E.Enhancement of photoinduced hydrogen production from irradiated Pt/TiO2 suspensions with simultaneous degradation of azo-dyes [J].Appl Catal,B:Environ, 2006, 64(3/4):171-179.
[13] 刘福生,吉仁,吴敏,等.苝染料敏化Pt/TiO2光催化分解水制氢 [J].物理化学学报,2007,23(12):1899-1904.
  Liu Fusheng,Ji Ren,Wu Min,et al.Study on the hydrogen production from water splitting using perylene dye-sensitized Pt/TiO2 photocatalyst [J].Acta Phys-Chim Sin,2007,23(12):1899-1904.(in Chinese)
[14] 刘福生,孙岳明,吴敏,等.N,N’-二吡啶基-3,4,9,10-苝四甲酰二亚胺衍生物及其合成方法:中国,200510094849.0[P].2005-10-17.
[15] Huang W,Yan D Y,Lu Q H,et al.Synthesis and characterization of highly soluble fluorescent main chain copolyimides containing perylene units [J].European Polymer Journal,2003,39(6):1099-1104.
[16] 牛海军,白续铎,黄玉东,等.含有p-n单元的苝聚酰亚胺的合成及其敏化光电池的性能研究[J].化学学报,2005,63(15):1391-1396.
  Niu Haijun,Bai Xuduo,Huang Yudong,et al.Synthesis and properties of perylene polyimide containing p-n diblock used in photovoltaic cell [J].Acta Chimica Sinica,2005,63(15):1391-1396.(in Chinese)

备注/Memo

备注/Memo:
作者简介: 刘福生(1962—),男,博士生,副教授; 孙岳明(联系人),男,博士,教授,博士生导师,sun@seu.edu.cn.
基金项目: 江苏省高技术研究基金资助项目(BG20055034)、教育部高等学校博士点科研基金资助项目(20030286012).
引文格式: 刘福生, 王晟,吴敏,等.染料的合成、表征及其光热性能[J].东南大学学报:自然科学版,2008,38(6):1049-1053.
更新日期/Last Update: 2008-11-20