[1]丁宽,仲兆平,余露露,等.城市固体废弃物混合热解特性及动力学[J].东南大学学报(自然科学版),2013,43(1):130-135.[doi:10.3969/j.issn.1001-0505.2013.01.025]
　Ding Kuan,Zhong Zhaoping,Yu Lulu,et al.Pyrolysis characteristics and kinetic study of mixed pyrolysis of municipal solid waste[J].Journal of Southeast University (Natural Science Edition),2013,43(1):130-135.[doi:10.3969/j.issn.1001-0505.2013.01.025]
点击复制

城市固体废弃物混合热解特性及动力学()
分享到：

《东南大学学报(自然科学版)》[ISSN:1001-0505/CN:32-1178/N]

卷:
43
期数:
2013年第1期
页码:
130-135
栏目:
环境科学与工程
出版日期:
2013-01-20

文章信息/Info

Title:
Pyrolysis characteristics and kinetic study of mixed pyrolysis of municipal solid waste
作者:
丁宽; 仲兆平; 余露露; 刘志超
东南大学能源热转换及其过程测控教育部重点实验室, 南京210096; 东南大学能源与环境学院, 南京210096
Author(s):
Ding Kuan;  Zhong Zhaoping;  Yu Lulu;  Liu Zhichao
Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Southeast University, Nanjing 210096, China
School of Energy and Environment, Southeast University, Nanjing 210096, China
关键词:
城市固体废弃物;  热解特性;  混合热解;  热重分析;  动力学
Keywords:
municipal solid waste;  pyrolysis characteristics;  mixed pyrolysis;  thermogravimetric analysis;  kinetic
分类号:
X705
DOI:
10.3969/j.issn.1001-0505.2013.01.025
摘要:
在研究城市固体废弃物(MSW)典型成分单组分失重规律的基础上,对两两组分混合热解相互影响进行了实验研究.结果表明:白菜、纸板和棉布热解主要分为3个阶段,而聚氯乙烯(PVC)和废轮胎的热解规律较复杂,但其热解过程可等效地看作2个和3个阶段,二者在前2个阶段失重率已经分别达到了100%和88%;两两组分混合后,对应阶段热解温度范围与单组分相比变化不大,而混合后热解速率则受到较大影响,说明所选组分两两混合对各单组分热解温度影响不明显,而热解产物或残留物可能会促进或抑制混合物的分解.根据单组分和混合组分原料的失重规律采用Coats-Redfern法分阶段进行动力学计算,结果表明:拟合曲线线性度很好,说明各单组分和混合组分热解过程分阶段处理是合理的;对于PVC和废轮胎单独热解和两两混合热解,将失重曲线上一些联系紧密的失重峰看作同一个失重阶段进行处理可获得更好的拟合线性度.
Abstract:
The interactions of pyrolysis in every two components were investigated by experiments based on the study of weight loss of single typical component of municipal solid waste(MSW). The results show that the pyrolysis of celery cabbage, cardboard and cotton cloth consist of three main stages. The pyrolysis characteristic of polyvinyl chloride(PVC)and waste tyre are relatively sophisticated, however they can be equiralently regarded as two and three stages, respectively. Their weight losses in the first two stages reach 100% and 88%, respectively. The corresponding pyrolysis temperature is slightly influenced by the blend of different components, while the rates are affected apparently. It can be concluded that the interactions of mixtures have little impact on the pyrolysis temperature. Moreover, the products or residues may promote or suppress the decomposition. The kinetic parameters of both single and mixed components were calculated in stages by the Coats-Redfern method according to weight loss. The results show that the fitting curves show good linearity, indicating that it is reasonable to deal with the pyrolysis of single and mixed components in stages. In addition, with regard to the single and mixed pyrolysis of PVC and waste tyre, better linearity can be obtained by treating weight loss peaks with tight relations as one stage.

参考文献/References:

[1] 王君,陈明强,张明旭,等.三种生物质的热解动力学研究[J].哈尔滨工业大学学报,2009,41(7):180-183.
　　Wang Jun, Chen Mingqiang, Zhang Mingxu, et al. Kinetic study on thermolysis of three different biomass species[J]. Journal of Harbin Institute of Technology, 2009, 41(7):180-183.(in Chinese)
[2] 赵巍,汪琦,刘海啸,等.热分析-质谱联用分析生物垃圾热解机理[J].环境科学与技术,2010,33(5):55-58.
　　Zhao Wei, Wang Qi, Liu Haixiao, et al. Pyrolysis mechanism of biomass waste with TA-MS[J]. Environmental Science & Technology, 2010, 33(5):55-58.(in Chinese)
[3] Miranda R, Blanco C S, Martinez D B,et al.Pyrolysis of textile wastes:I. kinetics and yields[J]. Journal of Analytical and Applied Pyrolysis, 2007, 80(2):489-495.
[4] 刘义彬,马晓波,陈德珍,等.废塑料典型组分共热解特性及动力学分析[J].中国电机工程学报,2010,30(23):56-61.
　　Liu Yibin, Ma Xiaobo, Chen Dezhen, et al. Copyrolysis characteristics and kinetic analysis of typical constituents of plastic wastes[J]. Proceedings of the CSEE, 2010, 30(23):56-61.(in Chinese)
[5] 薛旭方,于晗,洪楠,等.餐饮垃圾主要成分的热解动力学研究[J].环境工程学报,2010,4(10):2349-2354.
　　Xue Xufang, Yu Han, Hong Nan, et al. Kinetic study on pyrolysis of principal components of food residue[J]. Chinese Journal of Environmental Engineering, 2010, 4(10):2349-2354.(in Chinese)
[6] Sørum L, Grønli M G, Hustad J E. Pyrolysis characteristics and kinetic of municipal solid waste[J]. Fuel, 2001, 80(9):1217-1227.
[7] Kim S.Pyrolysis kinetics of waste PVC pipe[J]. Waste Management, 2001, 21(7):609-616.
[8] Matsuzawa Y, Ayabe M, Nishino J. Acceleration of cellulose co-pyrolysis with polymer[J].Polymer Degradation and Stability, 2001, 71(3):435-444.
[9] Pappa A, Mikedi K, Agapiou A, et al. TG-MS analysis of nitrile butadiene rubber blends(NBR/PVC)[J]. Journal of Analytical and Applied Pyrolysis, 2011, 92(1):106-110.
[10] Coats A W, Redfern J P.Kinetic parameters from thermogravimetric data[J]. Nature, 1964, 201(4914):68-69.

备注/Memo

备注/Memo:
作者简介: 丁宽(1988—),男,博士生;仲兆平(联系人),男,博士,教授,博士生导师,zzhong@seu.edu.cn.
基金项目: 国家重点基础研究发展计划(973计划)资助项目(2011CB201505).
引文格式: 丁宽,仲兆平,余露露,等.城市固体废弃物混合热解特性及动力学［J］.东南大学学报:自然科学版,2013,43(1):130-135. ［doi:10.3969/j.issn.1001-0505.2013.01.025］
更新日期/Last Update: 2013-01-20