[1]苏伟,刘倩,钟文琪,等.微型流化床中煤富氧燃烧特性[J].东南大学学报(自然科学版),2020,50(5):896-903.[doi:10.3969/j.issn.1001-0505.2020.05.015]
　Su Wei,Liu Qian,Zhong Wenqi,et al.Oxy-coal combustion characteristics in micro-fluidized bed reactor[J].Journal of Southeast University (Natural Science Edition),2020,50(5):896-903.[doi:10.3969/j.issn.1001-0505.2020.05.015]
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微型流化床中煤富氧燃烧特性()
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《东南大学学报(自然科学版)》[ISSN:1001-0505/CN:32-1178/N]

卷:
50
期数:
2020年第5期
页码:
896-903
栏目:
能源与动力工程
出版日期:
2020-09-20

文章信息/Info

Title:
Oxy-coal combustion characteristics in micro-fluidized bed reactor
作者:
苏伟; 刘倩; 钟文琪; 王晶振
东南大学能源热转换及其过程测控教育部重点实验室, 南京210096; 东南大学能源与环境学院, 南京210096
Author(s):
Su Wei;  Liu Qian;  Zhong Wenqi;  Wang Jingzhen
Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Southeast University, Nanjing 210096, China
School of Energy and Environment, Southeast University, Nanjing 210096, China
关键词:
富氧燃烧;  微型流化床;  动力学;  质谱
Keywords:
oxy-coal combustion;  micro-fluidized bed reaction analyzer;  kinetics;  mass spectrum
分类号:
TK16
DOI:
10.3969/j.issn.1001-0505.2020.05.015
摘要:
为了研究流化床锅炉中煤的富氧燃烧反应,将微型流化床反应分析仪和过程质谱仪(MFBRA-MS)联用,以烟煤和无烟煤标准煤样为对象,采用相对定量方法计算CO2浓度,研究了反应气氛、煤种等因素对煤粉在流化条件下快速燃烧反应动力学的影响.揭示了反应全过程中动力学参数的变化规律,并与热重条件下的实验结果进行对比,同时对主要气体产物的生成特性进行了跟踪和分析.结果表明,烟煤的活化能小于无烟煤,随着O2浓度的提高,煤富氧燃烧的活化能减小;相同氧浓度下,煤粉在O2/CO2气氛中燃烧活化能大于O2/Ar气氛;微型流化床中煤燃烧反应的活化能显著小于类似反应条件下热重分析获得的燃烧活化能.温度升高会缩短反应响应时间并使最大反应速率值增大,此时对应的转化率也增大.温度小于650 ℃不适宜煤粉燃烧,此时CO产量增加.O2浓度升高,CO2、NOx产量增加.相同条件下,煤粉在O2/CO2气氛中燃烧污染物产量少于O2/Ar气氛,这是由O2在不同气氛中扩散速率的差异所导致的.
Abstract:
To study the oxy-coal combustion reaction in a fluidized bed boiler, a micro-fluidized bed reactor and mass spectrum system(MFBRA-MS)was connected to study the standard coal samples of anthracite coal and bituminous coal. A relative quantitative method was used to calculate the concentration of CO2. The effects of reaction atmosphere, coal type on the rapid combustion reaction kinetics of coal particles under fluidized conditions and the formation characteristics of main gas products were tracked and analyzed. Changes in kinetic parameters during the entire process of reaction were found, the comparison was made between the thermogravimetric results and fluidized bed results. The results show the activation energy of bituminous coal is smaller than that of anthracite coal, with the increase of O2 concentration, the activation energy of coal oxy-fuel combustion decreases. On the same O2 concentration, the combustion activation energy of coal in O2/CO2 atmosphere is larger than that in O2/Ar atmosphere; the activation energy of oxy-coal combustion in MFBRA is significantly less than that obtained by thermogravimetric analysis under similar reaction conditions. The increase of the temperature is beneficial to shorten the response time of reaction and improve the maximum reaction rate, the corresponding conversion rate is bigger. Coal cannot combust well at 650 ℃ or lower, and the yields of CO increase. With the increase of O2 concentration, the yields of CO2 and NOx increase. Under similar condition, the yields of pollutants of coal in O2/CO2 is less than that of O2/Ar, it is due to the difference on diffusion rate of O2 in different atmospheres.

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备注/Memo

备注/Memo:
收稿日期: 2020-04-20.
作者简介: 苏伟(1994—),男,硕士生;钟文琪(联系人),男,博士,教授,博士生导师,wqzhong@seu.edu.cn.
基金项目: 国家自然科学基金重点资助项目(51736002)、国家重点研发计划资助项目(2016YFB0600802).
引用本文: 苏伟,刘倩,钟文琪,等.微型流化床中煤富氧燃烧特性[J].东南大学学报(自然科学版),2020,50(5):896-903. DOI:10.3969/j.issn.1001-0505.2020.05.015.
更新日期/Last Update: 2020-09-20