[1]傅剑锋.富里酸光电降解抑制三氯甲烷生成能机理[J].东南大学学报(自然科学版),2006,36(6):972-975.[doi:10.3969/j.issn.1001-0505.2006.06.020]
　Fu Jianfeng.Reduction of CHCl3 formation potential by photoelectrocatalytic oxidation of fulvic acid[J].Journal of Southeast University (Natural Science Edition),2006,36(6):972-975.[doi:10.3969/j.issn.1001-0505.2006.06.020]
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富里酸光电降解抑制三氯甲烷生成能机理()
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《东南大学学报(自然科学版)》[ISSN:1001-0505/CN:32-1178/N]

卷:
36
期数:
2006年第6期
页码:
972-975
栏目:
环境科学与工程
出版日期:
2006-11-20

文章信息/Info

Title:
Reduction of CHCl3 formation potential by photoelectrocatalytic oxidation of fulvic acid
作者:
傅剑锋
东南大学能源与环境学院, 南京 210096
Author(s):
Fu Jianfeng
School of Energy and Environment, Southeast University, Nanjing 210096, China
关键词:
光电催化氧化;  Ti/TiO2电极;  富里酸;  三氯甲烷生成能
Keywords:
photoelectrocatalytic oxidation;  Ti/TiO2 electrode;  fulvic acid;  chloroform formation potential
分类号:
X52
DOI:
10.3969/j.issn.1001-0505.2006.06.020
摘要:
验证了Ti/TiO2光电催化对富里酸降解有协同作用.对多孔Ti/TiO2光电降解富里酸前后影响三氯甲烷生成潜能做了机理探讨,考察了耗氯量、三氯甲烷生成能和荧光光谱图的变化过程,试验结果表明,随着富里酸TOC质量浓度的增加,三氯甲烷生成量逐渐增大,经过2 h的光电催化降解,耗氯量和三氯甲烷生成能分别被减少了72%和81%.荧光光谱图的变化也充分说明了经过光电催化氧化,富里酸溶液的荧光光强明显减弱,腐殖化程度降低,因此通过光电催化氧化可有效破坏富里酸的结构使得氯化过程产生的消毒副产物量大大减少.
Abstract:
A synergetic effect has been observed with combination of photocatalysis and electrocatalysis. The changes of chloroform formation potential during chlorination caused by Ti/TiO2 photoelectrocatalytic oxidation treatments were also investigated. The global changes observed during the treatment of the fulvic acid(FA)solution were directly connected to the chlorine demand, chloroform formation potential and fluorescence excitation-emission matrices spectra. Experiment results show that the chlorine demand and the trihalomethanes formation potential are reduced by 72% and 81% respectively after 2 h photoelectrooxidation. In addition, the fluorescence intensity of fulvic acid gradually decreases through photoelectrocatalytic oxidation treatment. Consequently, the FA degradation entails a drastic reduction of the chloroform formation potential due to the damage of FA structure.

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备注/Memo

备注/Memo:
基金项目: 教育部天南大合作基金资助项目(2002-2005).
作者简介: 傅剑锋(1976—),男,博士,讲师, fjf@seu.edu.cn.
更新日期/Last Update: 2006-11-20